Modifications of surface properties of a H2-treated RuS2/SiO2 catalyst:: A parallel between low-temperature COFTIR spectroscopy and model reactions

A silica-supported ruthenium sulfide catalyst was progressively reduced by hydrogen at increasing temperatures (423-673 K). The resulting modification of the surface properties was characterized by low-temperature CO adsorption FTIR spectroscopy and by test reactions such as CH3SH condensation and 1-butene hydrogenation. On the nonreduced catalyst, CO adsorption spectra showed the presence of bands, indicating various CO forms on Ru sites in a sulfur-rich environment. When sulfur was progressively removed from the ruthenium sulfide phase, the number of coordinatively unsaturated Ru sites increased with the simultaneous formation of metallic Ru microdomains. A comparison of measurements of adsorption and catalytic activity showed that a rich sulfur environment was needed for the condensation of CH3SH to CH3SCH3, a reaction that required acidic sites, while butene hydrogenation required highly depleted Ru sites. These results show that, upon reduction, RuS2 became less acidic and increasingly more metallic. (C) 2000 Academic Press.