Development of new Cu0-ZnII/Al2O3 catalyst supported on copper metallic foam for the production of hydrogen by methanol steam reforming

被引:17
作者
Catillon, S
Louis, C
Rouget, R
机构
[1] SCPS, F-93115 Rosny Sous Bois, France
[2] Univ Paris 06, LRS, UMR 7609, F-75252 Paris 5, France
关键词
metallic foam; methanol steam reforming; washcoat; Al2O3; copper zinc catalysts;
D O I
10.1023/B:TOCA.0000029838.42709.7c
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Copper metallic foam with thermal conductive properties, manufactured by S.C.P.S., has been investigated as a support for catalysts to improve thermal exchange inside the reactor for the endothermic steam reforming of methanol. Thus, we have developed a procedure for the in situ preparation of a Cu-0-Zn-II/Al2O3 catalyst onto the copper metallic foam. The foam-based Cu-0-Zn-II/Al2O3 catalyst shows an activity three times as high as commercial catalysts for a conversion of 74% of methanol into hydrogen.
引用
收藏
页码:463 / 467
页数:5
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