The Lennard-Jones-Devonshire cell model revisited

被引：13

作者：

Magee, JE

Wilding, NB ^{[1
]}

机构：

[1] Univ Liverpool, Dept Math Sci, Liverpool L69 7ZL, Merseyside, England

[2] Univ Edinburgh, Dept Phys & Astron, Edinburgh EH9 3JZ, Midlothian, Scotland

来源：

MOLECULAR PHYSICS | 2002年 / 100卷 / 10期

关键词：

D O I：

10.1080/00268970110117133

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The cell theory of Lennard-Jones and Devonshire is re-analysed and it is found that, in addition to the critical point originally reported for the 12-6 potential (and widely quoted in standard textbooks), the model exhibits a further critical point. The latter is shown to be actually a more appropriate candidate for liquid-gas criticality than the original critical point.

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页码：1641 / 1644

页数：4

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