Consecutive double nucleophilic attacks on an olefin promoted by a platinum(III) dimeric complex

被引：43

作者：

Lin, YS ^{[1
]}

Takeda, S ^{[1
]}

Matsumoto, K ^{[1
]}

机构：

[1] Waseda Univ, Japan Sci & Technol Corp, Adv Res Ctr Sci & Engn, Dept Chem,Shinjuku Ku, Tokyo 1698555, Japan

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 24期

关键词：

D O I：

10.1021/om990756a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The double-nucleophilic attacks of methanol and water successively on the two carbon atoms of a double bond of olefins was realized on a Pt(III) dimeric complex: to give the corresponding dinucleophile-substituted alkanes for the first time. Formation of the intermediate diplatinum(III) beta-methoxy and beta-hydroxyalkyl complexes was confirmed.

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收藏

页码：4897 / 4899

页数：3

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