Catalytic hydrogenation of 1-hexene with RuCl2(TPPMS)3(DMSO) Part II:: Ionic liquid biphasic system

被引：7

作者：

Suárez, T ^{[1
]}

Fontal, B ^{[1
]}

Reyes, M ^{[1
]}

Bellandi, F ^{[1
]}

Contreras, RR ^{[1
]}

Ortega, JM ^{[1
]}

León, G ^{[1
]}

Cancines, P ^{[1
]}

Castillo, B ^{[1
]}

机构：

[1] Univ Los Andes, Fac Ciencias, Dept Quim, Merida 5101, Venezuela

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 2004年 / 82卷 / 02期

关键词：

ruthenium; biphasic catalysis; hydrogenation; ionic liquid;

D O I：

10.1023/B:REAC.0000034844.21731.7f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

RuCl2(TPPMS)(3)(DMSO) (complex (1)) is very soluble in the ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate (BMI.PF6). Complex (1) catalyzes 1-hexene hydrogenation (500 psi H-2 and 100degreesC) in a two-phase system, with 80% conversion in 24 h, with little substrate isomerization. Changes in catalytic behavior with temperature, pressure, time and substrate/catalyst relation are presented. Complex (1) shows good stability and can be reused several times with little activity loss.

引用

页码：325 / 331

页数：7

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