Glycosylhydrazides, a new class of sugar surfactant.: Preparation and amphiphilic properties of 1-glycosyl-2-acylhydrazines

被引：16

作者：

Augé, J ^{[1
]}

Lubin-Germain, N ^{[1
]}

机构：

[1] Univ Cergy Pontoise, CNRS, Unite Associee, F-95031 Neuville Sur Oise, Cergy Pontoise, France

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 2000年 / 19卷 / 03期

关键词：

D O I：

10.1080/07328300008544085

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The synthesis and the amphiphilic properties of 1-glycosyl-2-acylhydrazines are described. This new class of surfactants, referred to as glycosylhydrazides, is easily available from a reducing sugar and hydrazides without protection. Seven hydrazides having an alkyl chain of up to fourteen carbon atoms, are coupled with glucose giving 1-glucosyl-2-acylhydrazines in good yields; 1-maltosyl-2-octanoylhydrazine, as a typical disaccharide-based surfactant, is prepared as well. Critical micellar concentrations of these surfactants range from 0.04 to 252 mM.

引用

页码：379 / 392

页数：14

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