The theoretical basis of the isoinversion principle

被引：32

作者：

Gypser, A

Norrby, PO

机构：

[1] Scripps Res Inst, DEPT CHEM BCC315, LA JOLLA, CA 92037 USA

[2] ROYAL DANISH SCH PHARM, DEPT CHEM, DK-2100 COPENHAGEN, DENMARK

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1997年 / 05期

关键词：

PATERNO-BUCHI REACTION; PHOTOCHEMICAL-REACTIONS; CHIRAL INDUCTION; REASSESSMENT;

D O I：

10.1039/a606888j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The theoretical basis of the isoinversion principle is discussed in terms of the temperature dependence of absolute rate constants. This description gives an insight into the origin and physical meaning of the terms 'inversion temperature' and 'transition region', The consequences of quantitative interpretation of nonlinear Eyring plots are discussed.

引用

页码：939 / 943

页数：5

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