Pickering emulsions with bare silica

被引:163
作者
Frelichowska, Justyna [1 ]
Bolzinger, Marie-Alexandrine [1 ]
Chevalier, Yves [1 ]
机构
[1] Univ Lyon 1, CNRS, Lab Automat & Genie Procedes,UMR 5007, Lab Dermopharm & Cosmetol,ISPB Fac Pharm, F-69622 Villeurbanne, France
关键词
Solid-stabilized emulsions; Pickering emulsions; Silica; Nanoparticles; Polar oils; IN-WATER EMULSIONS; PARTICLE-STABILIZED EMULSIONS; OIL; SURFACTANTS; EMULSIFICATION; NANOPARTICLES; WETTABILITY; INTERFACE; ANGLE;
D O I
10.1016/j.colsurfa.2009.01.031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Stabilization of o/w Pickering emulsions by fully hydrophilic fumed silica nanoparticles was successful upon selection of favorable oils. Silica particles were first dispersed in water as 100nm aggregates, and stable o/w emulsions of 2-10 mu m diameter were prepared using a standard rotor-stator device. The most relevant parameter allowing the selection of successful oils was the water-oil interfacial tension. The contact angle was difficult to manage with for predicting the stability because its measurement and its calculation were not accurate enough and the relevant differences were too small with that respect. The size of the stable emulsion was related to the silica content that fixed the interfacial area. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:70 / 74
页数:5
相关论文
共 28 条
[1]   Materials based on solid-stabilized emulsions [J].
Arditty, S ;
Schmitt, V ;
Giermanska-Kahn, J ;
Leal-Calderon, F .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 275 (02) :659-664
[2]   Some general features of limited coalescence in solid-stabilized emulsions [J].
Arditty, S ;
Whitby, CP ;
Binks, BP ;
Schmitt, V ;
Leal-Calderon, F .
EUROPEAN PHYSICAL JOURNAL E, 2003, 11 (03) :273-281
[3]   Emulsions stabilised solely by colloidal particles [J].
Aveyard, R ;
Binks, BP ;
Clint, JH .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2003, 100 :503-546
[4]   SURFACE INTERACTIONS OF DIMETHYLSILOXY GROUP-MODIFIED FUMED SILICA [J].
BARTHEL, H .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1995, 101 (2-3) :217-226
[5]  
Binks B. P., 2006, COLLOIDAL PARTICLES
[6]   Synergistic stabilization of emulsions by a mixture of surface-active nanoparticles and surfactant [J].
Binks, Bernard P. ;
Desforges, Alexandre ;
Duff, Daniel G. .
LANGMUIR, 2007, 23 (03) :1098-1106
[7]   Effects of oil type and aqueous phase composition on oil-water mixtures containing particles of intermediate hydrophobicity [J].
Binks, BP ;
Lumsdon, SO .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (13) :2959-2967
[8]   Nanoparticle silica-stabilised oil-in-water emulsions: improving emulsion stability [J].
Binks, BP ;
Whitby, CP .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 253 (1-3) :105-115
[9]   Silica particle-stabilized emulsions of silicone oil and water: Aspects of emulsification [J].
Binks, BP ;
Whitby, CP .
LANGMUIR, 2004, 20 (04) :1130-1137
[10]   Types of phase inversion of silica particle stabilized emulsions containing triglyceride oil [J].
Binks, BP ;
Rodrigues, JA .
LANGMUIR, 2003, 19 (12) :4905-4912