Systematic Improvement in Charge Carrier Mobility of Air Stable Triarylamine Copolymers

被引:188
作者
Zhang, Weimin [1 ,2 ]
Smith, Jeremy [1 ]
Hamilton, Rick [1 ]
Heeney, Martin [1 ]
Kirkpatrick, James [1 ]
Song, Kigook [3 ]
Watkins, Scott E. [4 ]
Anthopoulos, Thomas [1 ]
McCulloch, Iain [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, London SW7 2AZ, England
[2] Guangxi Univ Nationalities, Nanning 530006, Peoples R China
[3] Kyung Hee Univ, Yongin 446701, Gyeonggi Do, South Korea
[4] CSIRO Mol & Hlth Technol, Clayton, Vic 3169, Australia
基金
英国工程与自然科学研究理事会;
关键词
FIELD-EFFECT TRANSISTORS; ORGANIC SEMICONDUCTORS; POLYMERS;
D O I
10.1021/ja9034818
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The electrical performance of organic semiconducting polymers in field-effect transistor devices is now sufficient for initial low complexity circuit applications. To achieve high performance, either operation in an inert atmosphere or a hydrophobic surface treatment and annealing step is typically required. In this communication we report a strategy to prepare fully air stable, amorphous semiconducting polymers which can achieve charge carrier mobilities in the range of 0.04 cm(2)/(V s), remaining over a period of over 3 months in ambient conditions
引用
收藏
页码:10814 / +
页数:4
相关论文
共 15 条
[1]   Interaction of oxygen with conjugated polymers: Charge transfer complex formation with poly(3-alkylthiophenes) [J].
Abdou, MSA ;
Orfino, FP ;
Son, Y ;
Holdcroft, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4518-4524
[2]   Organic semiconductors for solution-processable field-effect transistors (OFETs) [J].
Allard, Sybille ;
Forster, Michael ;
Souharce, Benjamin ;
Thiem, Heiko ;
Scherf, Ullrich .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (22) :4070-4098
[3]   Enhanced mobility of poly(3-hexylthiophene) transistors by spin-coating from high-boiling-point solvents [J].
Chang, JF ;
Sun, BQ ;
Breiby, DW ;
Nielsen, MM ;
Sölling, TI ;
Giles, M ;
McCulloch, I ;
Sirringhaus, H .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4772-4776
[4]   Molecular basis of mesophase ordering in a thiophene-based copolymer [J].
DeLongchamp, Dean M. ;
Kline, R. Joseph ;
Jung, Youngsuk ;
Lin, Eric K. ;
Fischer, Daniel A. ;
Gundlach, David J. ;
Cotts, Sarah K. ;
Moad, Andrew J. ;
Richter, Lee J. ;
Toney, Michael F. ;
Heeney, Martin ;
McCulloch, Iain .
MACROMOLECULES, 2008, 41 (15) :5709-5715
[5]   Tetrathienoacene copolymers as high mobility, soluble organic semiconductors [J].
Fong, Hon Hang ;
Pozdin, Vladimir A. ;
Amassian, Aram ;
Malliaras, George G. ;
Smilgies, Detlef-M. ;
He, Mingqian ;
Gasper, Susan ;
Zhang, Feixia ;
Sorensen, Michael .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (40) :13202-13203
[6]  
Leeuw D.M., 1997, SYNTH MET, V87, P53
[7]   High-performance thin-film transistors from solution-processed dithienothiophene polymer semiconductor nanoparticles [J].
Li, Jun ;
Qin, Fang ;
Li, Chang Ming ;
Bao, Qiaoliang ;
Chan-Park, Mary B. ;
Zhang, Wei ;
Qin, Jingui ;
Ong, Beng S. .
CHEMISTRY OF MATERIALS, 2008, 20 (06) :2057-2059
[8]   Synthesis, characterization, and transistor response of semiconducting silole polymers with substantial hole mobility and air stability. Experiment and theory [J].
Lu, Gang ;
Usta, Hakan ;
Risko, Chad ;
Wang, Lian ;
Facchetti, Antonio ;
Ratner, Mark A. ;
Marks, Tobin J. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (24) :7670-7685
[9]   Dynamics of threshold voltage shifts in organic and amorphous silicon field-effect transistors [J].
Mathijssen, Simon G. J. ;
Colle, Michael ;
Gomes, Henrique ;
Smits, Edsger C. P. ;
de Boer, Bert ;
McCulloch, Iain ;
Bobbert, Peter A. ;
de Leeuw, Dago M. .
ADVANCED MATERIALS, 2007, 19 (19) :2785-+
[10]   Liquid-crystalline semiconducting polymers with high charge-carrier mobility [J].
Mcculloch, I ;
Heeney, M ;
Bailey, C ;
Genevicius, K ;
Macdonald, I ;
Shkunov, M ;
Sparrowe, D ;
Tierney, S ;
Wagner, R ;
Zhang, WM ;
Chabinyc, ML ;
Kline, RJ ;
Mcgehee, MD ;
Toney, MF .
NATURE MATERIALS, 2006, 5 (04) :328-333