The heterobimetallic polymeric zigzag chain [(W4S16Ag4)(4-)](n) derived from the linear chain [(WS4Ag)(-)](n): Synthesis, characterization, and structure of [W4S16Ag4.2Ca(DMSO)(6)](n) (DMSO=dimethyl sulfoxide)

被引：36

作者：

Huang, Q ^{[1
]}

Wu, XT ^{[1
]}

Lu, JX ^{[1
]}

机构：

[1] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,STATE KEY LAB STRUCT CHEM,FUZHOU 350002,FUJIAN,PEOPLES R CHINA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 25期

关键词：

D O I：

10.1021/ic9606791

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel heterobimetallic tungsten-silver-sulfur polymeric complex [W4S16Ag4 .-2Ca(DMSO)(6)](n) has been synthesized from addition of Ca(II) into a solution of the linear chain polymeric complex [WS4Ag . HNEt(3) . DMF](n) in DMSO. The anionic structure of this complex can be viewed as a zigzag chain.

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页码：7445 / &

页数：4

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