Preparation of C9-aldehyde via aldol condensation reactions in ionic liquid media

被引:72
作者
Mehnert, CP
Dispenziere, NC
Cook, RA
机构
[1] ExxonMobil Res & Engn Co, Corp Strateg Res, Annandale, NJ 08801 USA
[2] ExxonMobil Chem Co, Basic Chem & Intermediates Technol, Annandale, NJ 08801 USA
关键词
D O I
10.1039/b203068c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
C-9-aldehyde has been prepared via aldol condensation reactions in ionic liquid media; catalyst investigation showed enhanced product selectivity for the desired aldehyde in ionic liquid media than in conventional solvent systems.
引用
收藏
页码:1610 / 1611
页数:2
相关论文
共 17 条
[1]   Recent advances in solventless organic reactions: towards benign synthesis with remarkable versatility [J].
Cave, GWV ;
Raston, CL ;
Scott, JL .
CHEMICAL COMMUNICATIONS, 2001, (21) :2159-2169
[2]  
Chauvin Y, 1995, ANGEW CHEM INT EDIT, V34, P2698
[3]  
Cho TH, 1998, HIGH TEMP MATER P-US, V2, P543
[4]  
FALBE J, 1980, NEW SYNTHESES CARBON, P142
[5]  
Holbrey JD., 1999, CLEAN PRODUCTS PROCE, V1, P223, DOI [10.1007/s100980050036, DOI 10.1007/S100980050036]
[6]   Phase-separable catalysis using room temperature ionic liquids and supercritical carbon dioxide [J].
Liu, FC ;
Abrams, MB ;
Baker, RT ;
Tumas, W .
CHEMICAL COMMUNICATIONS, 2001, (05) :433-434
[7]  
March J., 1992, ADV ORG CHEM, P937
[8]   Nickel(II) heterocyclic carbene complexes as catalysts for olefin dimerization in an imidazolium chloroaluminate ionic liquid [J].
McGuinness, DS ;
Mueller, W ;
Wasserscheid, P ;
Cavell, KJ ;
Skelton, BW ;
White, AH ;
Englert, U .
ORGANOMETALLICS, 2002, 21 (01) :175-181
[9]   Continuous flow homogeneous catalysis: hydroformylation of alkenes in supercritical fluid-ionic liquid biphasic mixtures [J].
Sellin, MF ;
Webb, PB ;
Cole-Hamilton, DJ .
CHEMICAL COMMUNICATIONS, 2001, (08) :781-782
[10]   Catalytic reactions in ionic liquids [J].
Sheldon, R .
CHEMICAL COMMUNICATIONS, 2001, (23) :2399-2407