Direct synthesis of metal cluster complexes by deposition of mass-selected clusters with ligand: Iron with CO

被引：50

作者：

Fedrigo, S

Haslett, TL

Moskovits, M

机构：

[1] UNIV TORONTO,DEPT CHEM,TORONTO,ON M5S 1A1,CANADA

[2] ONTARIO LASER & LIGHTWAVE RES CTR,TORONTO,ON M5S 1A1,CANADA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1996年 / 118卷 / 21期

关键词：

D O I：

10.1021/ja954243g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new technique for preparing metal cluster complexes of a desired nuclearity by co-depositing ligand with metal clusters mass-selected from a cluster beam is illustrated by the deposition of Fe, Fe-2, and Fe-3 with excess CO. The matrices formed were studied by Fourier transform infrared spectroscopy. Unexpectedly, deposition of Fe-2 produced the CO-unbridged Fe-2(CO)(8) isomer, known primarily from matrix photochemistry, rather than the well-known diiron nonacarbonyl.

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页码：5083 / 5085

页数：3

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