Catalytic synthesis of multiwall carbon nanotubes from methylacetylene

被引:19
作者
Hernadi, K [1 ]
机构
[1] Univ Szeged, Dept Appl & Environm Chem, H-6720 Szeged, Hungary
关键词
D O I
10.1016/S0009-2614(02)01181-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Supported transition metal catalysts found to be active in the decomposition of acetylene were tested in the production of multiwall carbon nanotubes from methylacetylene. Monometallic (Co or Fe) and bimetallic (Fe,Co or Ni,V) samples were compared using three different types of catalyst support (silicagel, zeolite, alumina). Catalytic activity was characterized by the amount of deposited carbon, selectivity of carbon nanotube formation was estimated by transmission electron microscopy. Except for silica-supported catalysts, all samples were selective in MANT synthesis. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:169 / 174
页数:6
相关论文
共 29 条
[1]  
AVDEEVA LB, 1999, APPL CATAL A-GEN, V176, P135
[2]   CARBON FORMATION ON IRON AND NICKEL FOILS BY HYDROCARBON PYROLYSIS - REACTIONS AT 700DEGREESC [J].
BAIRD, T ;
FRYER, JR ;
GRANT, B .
CARBON, 1974, 12 (05) :591-602
[3]   FILAMENTOUS CARBON GROWTH ON NICKEL-IRON SURFACES - THE EFFECT OF VARIOUS OXIDE ADDITIVES [J].
BAKER, RTK ;
CHLUDZINSKI, JJ .
JOURNAL OF CATALYSIS, 1980, 64 (02) :464-478
[4]   Carbon nanotubes production by catalytic pyrolysis of benzene [J].
Benito, AM ;
Maniette, Y ;
Munoz, E ;
Martinez, MT .
CARBON, 1998, 36 (5-6) :681-683
[5]   THE FORMATION OF FILAMENTOUS CARBON ON IRON AND NICKEL-CATALYSTS .3. MORPHOLOGY [J].
BOELLAARD, E ;
DEBOKX, PK ;
KOCK, AJHM ;
GEUS, JW .
JOURNAL OF CATALYSIS, 1985, 96 (02) :481-490
[6]   Carbon nanofibers: Catalytic synthesis and applications [J].
De Jong, KP ;
Geus, JW .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2000, 42 (04) :481-510
[7]   Synthesis of single- and multi-wall carbon nanotubes over supported catalysts [J].
Fonseca, A ;
Hernadi, K ;
Piedigrosso, P ;
Colomer, JF ;
Mukhopadhyay, K ;
Doome, R ;
Lazarescu, S ;
Biro, LP ;
Lambin, P ;
Thiry, PA ;
Bernaerts, D ;
Nagy, JB .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1998, 67 (01) :11-22
[8]   Production of nanotubes by the catalytic decomposition of different carbon-containing compounds [J].
Hernadi, K ;
Fonseca, A ;
Nagy, JB ;
Siska, A ;
Kiricsi, I .
APPLIED CATALYSIS A-GENERAL, 2000, 199 (02) :245-255
[9]   Catalytic synthesis of carbon nanotubes using zeolite support [J].
Hernadi, K ;
Fonseca, A ;
Nagy, JB ;
Bernaerts, D ;
Fudala, A ;
Lucas, AA .
ZEOLITES, 1996, 17 (5-6) :416-423
[10]   Carbon nanotubes production over Co/silica catalysts [J].
Hernadi, K ;
Fonseca, A ;
Piedigrosso, P ;
Delvaux, M ;
Nagy, JB ;
Bernaerts, D ;
Riga, J .
CATALYSIS LETTERS, 1997, 48 (3-4) :229-238