A trinuclear double-helical metal complex of a quinquepyridine analog

被引：22

作者：

Baker, AT ^{[1
]}

Craig, DC ^{[1
]}

Dong, G ^{[1
]}

机构：

[1] UNIV NEW S WALES,SCH CHEM,SYDNEY,NSW 2052,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 05期

关键词：

D O I：

10.1021/ic951372p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A double-helical metal complex of an oligopyridine analog (i.e. with heterocycles other than pyridinyl rings) has been fully structurally characterized. This complex is the first example of a trinuclear double-helical complex containing quinquedentate and monodentate ligands and is of a type that has not been observed with the oligopyridines. In the rhetoric of metallosupramolecular chemistry much is said about the ''design'' of complexes of specific structure. Our work invites molecular engineers to consider pyrazolyl ligands as useful additions to their ''tool kit''.

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页码：1091 / &

页数：3

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