Stereoselectivity of triplet photocycloadditions, part 10 -: Oxazole-Carbonyl photocycloadditions:: selectivity pattern and synthetic route to erythro α-amino, β-hydroxy ketones

被引：32

作者：

Griesbeck, AG ^{[1
]}

Fiege, M ^{[1
]}

Lex, J ^{[1
]}

机构：

[1] Univ Cologne, Inst Organ Chem, D-50939 Cologne, Germany

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 07期

关键词：

D O I：

10.1039/b000578i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photocycloaddition of aliphatic and aromatic aldehydes with 2,4,5-trimethyloxazole proceeds highly regio- and diastereoselectively to give bicyclic oxetanes; hydrolytic cleavage of these adducts gives selectively erythro alpha-amino, beta-hydroxy methyl ketones.

引用

页码：589 / 590

页数：2

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