Fabrication of dye-sensitized solar cells using TiO2-nanotube arrays on Ti-grid substrates

被引:33
作者
Chun, K. Y. [1 ]
Park, B. W. [2 ]
Sung, Y. M. [2 ]
Kwak, D. J. [2 ]
Hyun, Y. T. [3 ]
Park, M. W. [1 ]
机构
[1] Kyungsung Univ, Dept Mat Engn, Pusan 608736, South Korea
[2] Kyungsung Univ, Dept Elect Engn, Pusan 608736, South Korea
[3] Korea Inst Machinery & Mat, Chang Won 641010, South Korea
关键词
Anodic oxidation; TiO2-nanotube; Photoanode; Dye-sensitized solar cells; NANOTUBE ARRAYS; ANODIZATION;
D O I
10.1016/j.tsf.2009.02.042
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Self-aligned TiO2 nanotube arrays (20 mu m in length) were fabricated by anodic oxidation of Ti-grid with a thickness of 100 mu m in an ethylene glycol electrolyte with an addition of H2O (1.5 vol.%) and NH4F (0.2 wt.%). Voltage applied between Ti and Pt cathodes is 60 V at -22 degrees C. Dye-sensitized solar cell utilizing photoanode structure of TiO2-nanotube/Ti-grid was fabricated with no transparent conducting oxide (TCO) layer, in which Ti-grid replaces TCO. Overall photoconversion efficiency is very low (<05%) due to the large pore size (100 nm in diameter) of the nanotubes, which may cause insufficient dye molecules to be attached, thus limiting light harvesting. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:4196 / 4198
页数:3
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