The O52 network by molecular design: CECD tetrablock terpolymers

被引：14

作者：

Bluemle, Michael J. ^{[1
]}

Fleury, Guillaume ^{[1
]}

Lodge, Timothy P. ^{[1
,2
]}

Bates, Frank S. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA

[2] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

SOFT MATTER | 2009年 / 5卷 / 08期

基金：

美国国家科学基金会;

关键词：

TRIBLOCK COPOLYMERS; BLOCK-COPOLYMERS; SOFT MATERIALS; MORPHOLOGY; MELTS; WEIGHT; PHASES;

D O I：

10.1039/b902367d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

Varying the length of poly(dimethylsiloxane) in poly(cyclohexylethylene-b-ethylene-b-cyclohexylethylene-b-dimethylsiloxane) (CECD) block terpolymers between 0 and 20% produces the sequence of ordered phases: cylindrical-to-network-to-cylindrical. Small-angle X-ray scattering and transmission electron microscopy demonstrate Pnna space group symmetry and a unique network morphology stabilized by the asymmetric molecular architecture and block interactions. These results establish a new design principle for the generation of triply periodic and multiply continuous nano-structured soft materials.

引用

页码：1587 / 1590

页数：4

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