Effects of microstructure of anodic titania on the formation of bioactive compounds

被引:47
作者
Lee, Jong-Ho
Kim, Seung-Eon
Kim, Young-Jig
Chi, Choong-Soo
Oh, Han-Jun [1 ]
机构
[1] Hanseo Univ, Dept Mat Sci, Seosan 352820, South Korea
[2] Hanseo Univ, Dept Chem, Seosan 352820, South Korea
[3] Korea Inst Machinery & Mat, Chang Won 641010, South Korea
[4] Sungkyunkwan Univ, Dept Met Engn, Suwon 440746, South Korea
[5] Kookmin Univ, Sch Met & Mat Engn, Seoul 136702, South Korea
关键词
biomaterials; electrochemical techniques; energy dispersive analysis of X-rays (EDS); x-ray photoemission spectroscopy (XPS);
D O I
10.1016/j.matchemphys.2005.08.058
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
To improve preferential nucleation of calcium phosphate by attractive interaction between Ca2+ ion in biological fluid and titania surface, negatively charged porous titanium oxide films for implant applications were synthesized by electrochemical process in electrolyte of 1.5 M sulfuric acid containing phosphoric acid as air additive, and the effects of surface characteristics of anodic titania on the formation of bioactive apatite were investigated. More nucleation capability of bioactive Ca-P compound was shown on the anodic film formed in high concentration of phosphoric acid electrolyte compared with lower concentration of phosphoric acid. The incorporated phosphate species were found mostly in the forms of HPO4-, PO4-, and PO3-. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:39 / 43
页数:5
相关论文
共 13 条
[1]   APATITE COATING ON CERAMICS, METALS AND POLYMERS UTILIZING A BIOLOGICAL PROCESS [J].
ABE, Y ;
KOKUBO, T ;
YAMAMURO, T .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1990, 1 (04) :233-238
[2]   Characterization of titanium surfaces with calcium and phosphate and osteoblast adhesion [J].
Feng, B ;
Weng, J ;
Yang, BC ;
Qu, SX ;
Zhang, XD .
BIOMATERIALS, 2004, 25 (17) :3421-3428
[3]   HETEROGENEOUS PHOTOCATALYSIS [J].
FOX, MA ;
DULAY, MT .
CHEMICAL REVIEWS, 1993, 93 (01) :341-357
[4]   Thin hydroxyapatite coatings via sol-gel synthesis [J].
Gross, KA ;
Chai, CS ;
Kannangara, GSK ;
Ben-Nissan, B ;
Hanley, L .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1998, 9 (12) :839-843
[5]   GROWTH OF A BONELIKE APATITE LAYER ON A SUBSTRATE BY A BIOMIMETIC PROCESS [J].
HATA, K ;
KOKUBO, T ;
NAKAMURA, T ;
YAMAMURO, T .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (04) :1049-1053
[6]   Properties of TiO2 film prepared from titanium tetrachloride [J].
Kim, GH ;
Lee, CG ;
Kim, I .
METALS AND MATERIALS INTERNATIONAL, 2004, 10 (05) :423-427
[7]   Preparation of photocatalytic TiO2-SiO2 thin film by sol-gel coating [J].
Lee, DH ;
Choi, SY .
METALS AND MATERIALS INTERNATIONAL, 2004, 10 (04) :357-360
[8]   XPS characterization of anodic titanium oxide films grown in phosphate buffer solutions [J].
Marino, CEB ;
Nascente, PAP ;
Biaggio, SR ;
Rocha, RC ;
Bocchi, N .
THIN SOLID FILMS, 2004, 468 (1-2) :109-112
[9]   MECHANICAL-PROPERTIES OF HYDROXYAPATITE FORMED AT PHYSIOLOGICAL TEMPERATURE [J].
MARTIN, RI ;
BROWN, PW .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1995, 6 (03) :138-143
[10]   Microstructural characterization of biomedical titanium oxide film fabricated by electrochemical method [J].
Oh, HJ ;
Lee, JH ;
Jeong, Y ;
Kim, YJ ;
Chi, CS .
SURFACE & COATINGS TECHNOLOGY, 2005, 198 (1-3) :247-252