Electrochemical reduction of nickel complexes with 2,2′-bipyridine

被引：26

作者：

Budnikova, YG ^{[1
]}

Yakhvarov, DG

Morozov, VI

Kargin, YM

Il'yasov, AV

Vyakhireva, YN

Sinyashin, OG

机构：

[1] Russian Acad Sci, Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, Kazan, Tatarstan, Russia

[2] Kazan VI Lenin State Univ, Kazan 420008, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 02期

关键词：

Nickel; Active Form; Bipyridine; Electrochemical Reduction; Ligand Concentration;

D O I：

10.1023/A:1015401029839

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical reduction of a nickel complex with 2,2'-bipyridine is accompanied by competing coproportionation yielding paramagnetic Ni-I complexes. A decrease in the ligand concentration shifts the equilibrium to the side of the active form of the Ni(o)bipy catalyst.

引用

页码：168 / 172

页数：5

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