Catalytic and asymmetric cyclopropanation of styrenes catalysed by ruthenium porphyrin and porphycene complexes

被引：134

作者：

Lo, WC

Che, CM

Cheng, KF

Mak, TCW

机构：

[1] UNIV HONG KONG,DEPT CHEM,HONG KONG,HONG KONG

[2] CHINESE UNIV HONG KONG,DEPT CHEM,SHATIN,NEW TERRITORIES,HONG KONG

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 13期

关键词：

D O I：

10.1039/a608080d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium porphyrin and porphycene complexes catalyse stereospecific cyclopropanation of styrenes; high product turnovers with up to 90.8% ee were achieved with the [Ru(P*)(CO)(EtOH)] catalyst (H2P* = chiral D-4 porphyrin).

引用

页码：1205 / 1206

页数：2

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