Solvothermal preparation of amorphous carbon nanotubes and Fe/C coaxial nanocables from sulfur, ferrocene, and benzene

被引:49
作者
Luo, Tao
Chen, Luyang
Bao, Keyan
Yu, Weichao
Qian, Yitai [1 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Anhua 230026, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
carbon nanotubes; catalyst; electron microscopy;
D O I
10.1016/j.carbon.2006.03.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Amorphous carbon nanotubes and Fe/C coaxial nanocables were synthesized by a solvothermal treatment of ferrocene and sulfur. In this process, the amount of sulfur played an important role in the formation of products. When the molar ratio of ferrocene to sulfur was 1: 1, the products were amorphous carbon nanotubes and Fe/C coaxial nanocables. And as the ratio was decreased to 1:2, amorphous carbon nanotubes were the main products. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2844 / 2848
页数:5
相关论文
共 22 条
[1]   COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS [J].
BETHUNE, DS ;
KIANG, CH ;
DEVRIES, MS ;
GORMAN, G ;
SAVOY, R ;
VAZQUEZ, J ;
BEYERS, R .
NATURE, 1993, 363 (6430) :605-607
[2]   Large-scale and low-cost synthesis of single-walled carbon nanotubes by the catalytic pyrolysis of hydrocarbons [J].
Cheng, HM ;
Li, F ;
Su, G ;
Pan, HY ;
He, LL ;
Sun, X ;
Dresselhaus, MS .
APPLIED PHYSICS LETTERS, 1998, 72 (25) :3282-3284
[3]   Annealing amorphous carbon nanotubes for their application in hydrogen storage [J].
Ci, LJ ;
Zhu, HW ;
Wei, BQ ;
Xu, CL ;
Wu, DH .
APPLIED SURFACE SCIENCE, 2003, 205 (1-4) :39-43
[4]   Single-wall nanotubes produced by metal-catalyzed disproportionation of carbon monoxide [J].
Dal, HJ ;
Rinzler, AG ;
Nikolaev, P ;
Thess, A ;
Colbert, DT ;
Smalley, RE .
CHEMICAL PHYSICS LETTERS, 1996, 260 (3-4) :471-475
[5]   LARGE-SCALE SYNTHESIS OF CARBON NANOTUBES [J].
EBBESEN, TW ;
AJAYAN, PM .
NATURE, 1992, 358 (6383) :220-222
[6]   EFFECT OF HYDROGEN ON THE MORPHOLOGY OF CARBON DEPOSITED FROM THE CATALYTIC DISPROPORTIONATION OF CO [J].
HERREYRE, S ;
GADELLE, P .
CARBON, 1995, 33 (02) :234-237
[7]   Synthesis of carbon nanotube bundles with mesoporous structure by a self-assembly solvothermal route [J].
Hu, G ;
Cheng, MJ ;
Ma, D ;
Bao, XH .
CHEMISTRY OF MATERIALS, 2003, 15 (07) :1470-1473
[8]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[9]   FORMATION OF CARBON-FIBERS FROM NAPHTHALENE ON SOME SULFUR-CONTAINING SUBSTRATES [J].
KATSUKI, H ;
MATSUNAGA, K ;
EGASHIRA, M ;
KAWASUMI, S .
CARBON, 1981, 19 (02) :148-150
[10]   Fabrication of SiC-C coaxial nanocables: thickness control of C outer layers [J].
Kim, HY ;
Bae, SY ;
Kim, NS ;
Park, J .
CHEMICAL COMMUNICATIONS, 2003, (20) :2634-2635