Alternating copolymers of fluorene and donor-acceptor-donor segments designed for miscibility in bulk heterojunction photovoltaics

被引:26
作者
Gedefaw, Desta [1 ]
Zhou, Yi [2 ]
Hellstrom, Stefan [1 ]
Lindgren, Lars [1 ]
Andersson, L. Mattias [2 ,3 ]
Zhang, Fengling [2 ,3 ]
Mammo, Wendimagegn [1 ]
Inganas, Olle [2 ,3 ]
Andersson, Mats R. [1 ,3 ]
机构
[1] Chalmers, Dept Chem & Biol Engn, S-41296 Gothenburg, Sweden
[2] Linkoping Univ, IFM, SE-58183 Linkoping, Sweden
[3] Linkoping Univ, COE, SE-58183 Linkoping, Sweden
关键词
POLYMER SOLAR-CELLS; POLYFLUORENE COPOLYMER; PERFORMANCE;
D O I
10.1039/b823137k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel copolymer based on alternating fluorene and donor-acceptor-donor segments is reported, together with its photovoltaic properties in blends with fullerene derivatives. The balanced electron and hole mobility of the blends leads to a power-conversion efficiency of 2-3% under solar illumination.
引用
收藏
页码:5359 / 5363
页数:5
相关论文
共 11 条
[1]   Stoichiometry, mobility, and performance in bulk heterojunction solar cells [J].
Andersson, L. Mattias ;
Zhang, Fengling ;
Inganaes, Olle .
APPLIED PHYSICS LETTERS, 2007, 91 (07)
[2]   A new donor-acceptor-donor polyfluorene copolymer with balanced electron and hole mobility [J].
Gadisa, Abay ;
Mammo, Wendimagegn ;
Andersson, L. Mattias ;
Admassie, Shimelis ;
Zhang, Fengling ;
Andersson, Mats R. ;
Inganas, Olle .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (18) :3836-3842
[3]   Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols [J].
Peet, J. ;
Kim, J. Y. ;
Coates, N. E. ;
Ma, W. L. ;
Moses, D. ;
Heeger, A. J. ;
Bazan, G. C. .
NATURE MATERIALS, 2007, 6 (07) :497-500
[4]   Thienyl analog of 1-(3-methoxycarbonyl)propyl-1-phenyl-[6,6]-methanofullerene for bulk heterojunction photovoltaic devices in combination with polythiophenes [J].
Popescu, Lacramioara M. ;
van't Hof, Patrick ;
Sieval, Alexander B. ;
Jonkman, Harry T. ;
Hummelen, Jan C. .
APPLIED PHYSICS LETTERS, 2006, 89 (21)
[5]   2.5% efficient organic plastic solar cells [J].
Shaheen, SE ;
Brabec, CJ ;
Sariciftci, NS ;
Padinger, F ;
Fromherz, T ;
Hummelen, JC .
APPLIED PHYSICS LETTERS, 2001, 78 (06) :841-843
[6]   High-performance polymer solar cells of an alternating polyfluorene copolymer and a fullerene derivative [J].
Svensson, M ;
Zhang, FL ;
Veenstra, SC ;
Verhees, WJH ;
Hummelen, JC ;
Kroon, JM ;
Inganäs, O ;
Andersson, MR .
ADVANCED MATERIALS, 2003, 15 (12) :988-+
[7]   Infrared photocurrent spectral response from plastic solar cell with low-band-gap polyfluorene and fullerene derivative [J].
Wang, XJ ;
Perzon, E ;
Delgado, JL ;
de la Cruz, P ;
Zhang, FL ;
Langa, F ;
Andersson, M ;
Inganäs, O .
APPLIED PHYSICS LETTERS, 2004, 85 (21) :5081-5083
[8]   Effect of solvent mixture on the nanoscale phase separation in polymer solar cells [J].
Yao, Yan ;
Hou, Jianhui ;
Xu, Zheng ;
Li, Gang ;
Yang, Yang .
ADVANCED FUNCTIONAL MATERIALS, 2008, 18 (12) :1783-1789
[9]   High photovoltage achieved in low band gap polymer solar cells by adjusting energy levels of a polymer with the LUMOs of fullerene derivatives [J].
Zhang, Fengling ;
Bijleveld, Johan ;
Perzon, Erik ;
Tvingstedt, Kristofer ;
Barrau, Sophie ;
Inganaes, Olle ;
Andersson, Mats R. .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (45) :5468-5474
[10]   Low-bandgap alternating fluorene copolymer/methanofullerene heterojunctions in efficient near-infrared polymer solar cells [J].
Zhang, Fengling ;
Mammo, Wendimagegn ;
Andersson, Lars M. ;
Admassie, Shimelis ;
Andersson, Mats R. ;
Inganas, Lars ;
Admassie, Shimelis ;
Andersson, Mats R. ;
Inganas, Olle .
ADVANCED MATERIALS, 2006, 18 (16) :2169-+