Molybdenum trioxide nanostructures prepared by thermal oxidization of molybdenum

被引：93

作者：

Ding, Q. P. ^{[1
]}

Huang, H. B. ^{[1
]}

Duan, J. H. ^{[1
]}

Gong, J. F. ^{[1
]}

Yang, S. G. ^{[1
]}

Zhao, X. N. ^{[1
]}

Du, Y. W. ^{[1
]}

机构：

[1] Nanjing Univ, Natl Lab Microstruct, Nanjing 210093, Peoples R China

来源：

JOURNAL OF CRYSTAL GROWTH | 2006年 / 294卷 / 02期

基金：

中国国家自然科学基金;

关键词：

crystal morphology; low dimensional structures; nanostructures; growth from vapor; nanomaterials; oxides;

D O I：

10.1016/j.jcrysgro.2006.07.004

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Molybdenum trioxide (MoO3) nanobelts and microballs were prepared by oxidization of molybdenum metal in an ambient atmosphere. Their lattice structures and morphologies were carefully studied by X-ray diffraction (XRD), Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM). The as-synthesized nanobelts and mircoballs are orthorhombic and monoclinic structured, respectively. The nanobelts are up to several hundred microns long, several hundred nanometers to several microns wide, with ratio of width to thickness between 5 and 10. HRTEM suggests the nanobelts grow along the [001] direction. The microballs are 3-10 mu m in diameter. Raman spectroscopy and Fourier transform infrared spectroscopy (FTIR) studies revealed the stretching vibration modes of Mo-O bonds as in alpha-MoO3 nanobelts. The possible growth mechanism of the nanobelts was discussed. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：304 / 308

页数：5

共 28 条

[1] Single crystal SnO2 zigzag nanobelts [J].

Duan, JH ;

Yang, SG ;

Liu, HW ;

Gong, JF ;

Huang, HB ;

Zhao, XN ;

Zhang, R ;

Du, YW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (17) :6180-6181

[2] LONGITUDINAL TRANSVERSE SPLITTING EFFECTS IN IR-ABSORPTION-SPECTRA OF MOO3 [J].

EDA, K .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 95 (01) :64-73

[3] ELECTROCHROMIC MATERIALS - MICROSTRUCTURE, ELECTRONIC BANDS, AND OPTICAL-PROPERTIES [J].

GRANQVIST, CG .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1993, 57 (01) :3-12

[4] Micro-Raman characterization of WO3 and MoO3 thin films obtained by pulsed laser irradiation [J].

Haro-Poniatowski, E ;

Jouanne, M ;

Morhange, JF ;

Julien, C ;

Diamant, R ;

Fernandez-Guasti, M ;

Fuentes, GA ;

Alonso, JC .

APPLIED SURFACE SCIENCE, 1998, 127 :674-678

[5] Synthesis of polypyrrole/MoO3 hybrid thin films and their volatile organic compound gas-sensing properties [J].

Hosono, K ;

Matsubara, I ;

Murayama, N ;

Woosuck, S ;

Izu, N .

CHEMISTRY OF MATERIALS, 2005, 17 (02) :349-354

[6] Controllable assembly of aligned ZnO nanowires/belts arrays [J].

Huang, HB ;

Yang, SG ;

Gong, JF ;

Liu, HW ;

Duan, JH ;

Zhao, XN ;

Zhang, R ;

Liu, YL ;

Liu, YC .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (44) :20746-20750

[7] Surfactant-mediated incorporation of poly(p-phenylene) into MoO3 [J].

Kerr, TA ;

Leroux, F ;

Nazar, LF .

CHEMISTRY OF MATERIALS, 1998, 10 (10) :2588-2591

[8]

KIHLBORG L, 1963, ARK KEMI, V21, P357

[9] Semiconductor nanowires and nanotubes [J].

Law, M ;

Goldberger, J ;

Yang, PD .

ANNUAL REVIEW OF MATERIALS RESEARCH, 2004, 34 :83-122

[10] Low-temperature synthesis of large-scale single-crystal molybdenum trioxide (MoO3) nanobelts [J].

Li, XL ;

Liu, JF ;

Li, YD .

APPLIED PHYSICS LETTERS, 2002, 81 (25) :4832-4834

← 1 2 3 →