A hybrid phosphorus ligand for highly enantioselective asymmetric hydroformylation

被引：188

作者：

Yan, Yongjun ^{[1
]}

Zhang, Xumu ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 22期

关键词：

D O I：

10.1021/ja057065s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new hybrid phosphorus ligand has been prepared starting from chiral NOBIN (2-amino-2'-hydroxy-1,1'-binaphthyl). Excellent enantioselectivities (up to 99% ee) have been achieved in the Rh-catalyzed asymmetric hydroformylations of styrene derivatives and vinyl acetate.

引用

页码：7198 / 7202

页数：5

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