Easily-prepared dinickel phosphide (Ni2P) nanoparticles as an efficient and robust electrocatalyst for hydrogen evolution

被引：392

作者：

Feng, Ligang ^{[1
]}

Vrubel, Heron ^{[1
]}

Bensimon, Michael ^{[2
]}

Hu, Xile ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, ISIC LSCI, BCH 3305, Lab Inorgan Synth & Catalysis,Inst Chem Sci & Eng, CH-1015 Lausanne, Switzerland

[2] Ecole Polytech Fed Lausanne, Inst Environm Engn, Gen Environm Lab, CH-1015 Lausanne, Switzerland

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2014年 / 16卷 / 13期

基金：

欧洲研究理事会;

关键词：

NICKEL PHOSPHIDE; MOLYBDENUM; CATALYSTS; ELECTRODES; ADSORPTION; SURFACE; MOS2;

D O I：

10.1039/c4cp00482e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polydispersed dinickel phosphide (Ni2P) nanoparticles were synthesized by a simple and scalable solid-state reaction. These nanoparticles are an excellent and robust catalyst for the electrochemical hydrogen evolution reaction, operating in both acidic and basic solutions.

引用

收藏

页码：5917 / 5921

页数：5

相关论文

共 22 条

[1] THE MECHANISM OF THE CATHODIC HYDROGEN EVOLUTION REACTION [J].

BOCKRIS, JOM ;

POTTER, EC .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1952, 99 (04) :169-186

[2] Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production [J].

Chen, W. -F. ;

Wang, C. -H. ;

Sasaki, K. ;

Marinkovic, N. ;

Xu, W. ;

Muckerman, J. T. ;

Zhu, Y. ;

Adzic, R. R. .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (03) :943-951

[3] Hydrogen-Evolution Catalysts Based on Non-Noble Metal Nickel-Molybdenum Nitride Nanosheets [J].

Chen, Wei-Fu ;

Sasaki, Kotaro ;

Ma, Chao ;

Frenkel, Anatoly I. ;

Marinkovic, Nebojsa ;

Muckerman, James T. ;

Zhu, Yimei ;

Adzic, Radoslav R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (25) :6131-6135

[4]

Conway B.E., 1964, Electrochimica Acta, V9, P1599, DOI DOI 10.1016/0013-4686(64)80088-8

[5]

Kibsgaard J, 2012, NAT MATER, V11, P963, DOI [10.1038/NMAT3439, 10.1038/nmat3439]

[6] Molybdenum sulfides-efficient and viable materials for electro - and photoelectrocatalytic hydrogen evolution [J].

Laursen, Anders B. ;

Kegnaes, Soren ;

Dahl, Soren ;

Chorkendorff, Ib .

ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (02) :5577-5591

[7] Powering the planet: Chemical challenges in solar energy utilization [J].

Lewis, Nathan S. ;

Nocera, Daniel G. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2006, 103 (43) :15729-15735

[8] MoS2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction [J].

Li, Yanguang ;

Wang, Hailiang ;

Xie, Liming ;

Liang, Yongye ;

Hong, Guosong ;

Dai, Hongjie .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (19) :7296-7299

[9] Catalysts for hydrogen evolution from the [NiFe] hydrogenase to the Ni2P(001) surface:: The importance of ensemble effect [J].

Liu, P ;

Rodriguez, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (42) :14871-14878

[10] Ni2P/Graphene Sheets as Anode Materials with Enhanced Electrochemical Properties versus Lithium [J].

Lu, Yi ;

Wang, Xiuli ;

Mai, Yongjin ;

Xiang, Jiayuan ;

Zhang, Heng ;

Li, Lu ;

Gu, Changdong ;

Tu, Jiangping ;

Mao, Scott X. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (42) :22217-22225