Transannular Diels-Alder reaction studies with an activated dienophile. An enantioselective synthesis of an A.B.C.[6.6.6.] trans-syn-cis tricycle.

被引：12

作者：

Barriault, L ^{[1
]}

Ouellet, SG ^{[1
]}

Deslongchamps, P ^{[1
]}

机构：

[1] UNIV SHERBROOKE,FAC SCI,DEPT CHIM,ORGAN SYNTH LAB,SHERBROOKE,PQ J1K 2R1,CANADA

来源：

TETRAHEDRON | 1997年 / 53卷 / 44期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0040-4020(97)00997-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis and transannular Diels-Alder reaction of a chiral 14 membered trans-cis-cis (TCC) macrocyclic triene with an activated dienophile leading to an A.B.C.[6.6.6.] tricyclic compound are described. The outcome of the TADA reaction under thermal and catalyzed conditions is discussed. (C) 1997 Elsevier Science Ltd.

引用

页码：14937 / 14956

页数：20

共 32 条

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