2,8-Dibromo-6H, 12H-5,11-methanodibenzo[b,f][1,5]diazocine

被引:15
作者
Faroughi, Masoud
Try, Andrew C.
Turner, Peter
机构
[1] Macquarie Univ, Dept Chem & Biomol Sci, N Ryde, NSW 2109, Australia
[2] Univ Sydney, Dept Chem, Sydney, NSW 2000, Australia
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词
D O I
10.1107/S1600536806029886
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the molecule of the title compound, C15H12Br2N2, the 2,8-dibromo analogue of Troger's base, the two aryl rings are offset with respect to one another by virtue of the diazocine bridge. The dihedral angle between the two benzene rings is 94.45 (4)degrees.
引用
收藏
页码:O3674 / O3675
页数:2
相关论文
共 19 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]   SIR97:: a new tool for crystal structure determination and refinement [J].
Altomare, A ;
Burla, MC ;
Camalli, M ;
Cascarano, GL ;
Giacovazzo, C ;
Guagliardi, A ;
Moliterni, AGG ;
Polidori, G ;
Spagna, R .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119
[3]  
*BRUK AXS INC, 1995, SMART SAINT XPREP
[4]   GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].
CREMER, D ;
POPLE, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358
[5]  
Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020
[6]  
HALL SR, 1999, XTAL3 6 SYSTEM
[7]   Synthesis of dihalo-substituted analogues of Troger's base from ortho- and meta-substituted anilines [J].
Hansson, A ;
Jensen, J ;
Wendt, OF ;
Wärnmark, K .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (16) :3179-3188
[8]   Preparation of Troger base derivatives by cross-coupling methodologies [J].
Hof, F ;
Schär, M ;
Scofield, DM ;
Fischer, F ;
Diederich, F ;
Sergeyev, S .
HELVETICA CHIMICA ACTA, 2005, 88 (08) :2333-2344
[9]  
Jensen J, 2002, SYNTHESIS-STUTTGART, P2761
[10]   General protocols for the synthesis of C2-symmetric and asymmetric 2,8-disubstituted analogues of Troger's base via efficient bromine-lithium exchanges of 2,8-dibromo-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine [J].
Jensen, J ;
Tejler, J ;
Wärnmark, K .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (17) :6008-6014