Synthesis and Structure Characterization of Copper Terephthalate Metal-Organic Frameworks

被引：331

作者：

Carson, Cantwell G. ^{[1
]}

Hardcastle, Kenneth ^{[2
]}

Schwartz, Justin ^{[3
,4
]}

Liu, Xiaotao ^{[4
]}

Hoffmann, Christina ^{[5
]}

Gerhardt, Rosario A. ^{[1
]}

Tannenbaum, Rina ^{[1
,6
]}

机构：

[1] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA

[2] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

[3] Florida State Univ, Natl High Magnet Field Lab, Tallahassee, FL 32310 USA

[4] Florida State Univ, Coll Engn, Florida A&M Univ, Dept Mech Engn, Tallahassee, FL 32310 USA

[5] Oak Ridge Natl Lab, NSSD, Spallat Neutron Source, Oak Ridge, TN 37831 USA

[6] Technion Israel Inst Technol, Dept Chem Engn, IL-32000 Haifa, Israel

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 16期

关键词：

Microporous materials; Coordination polymers; Crystal engineering; Magnetic properties; Carboxylate ligands; Metal-organic frameworks; VIBRATIONAL-SPECTRA; SOLVOTHERMAL SYNTHESIS; COORDINATION POLYMERS; MAGNETIC-PROPERTIES; DIMETHYL FORMAMIDE; ADSORPTION; DESIGN; TRANS-1,4-CYCLOHEXANEDICARBOXYLATE; ELECTROCHEMISTRY; MOLECULES;

D O I：

10.1002/ejic.200801224

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2338 / 2343

页数：6

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