Trans additions of silanes to 1-alkynes catalyzed by ruthenium complexes:: Role of in situ formed polynuclear aggregates

被引：35

作者：

Martín, M ^{[1
]}

Sola, E ^{[1
]}

Lahoz, FJ ^{[1
]}

Oro, LA ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Dept Quim Inorgan, E-50009 Zaragoza, Spain

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 20期

关键词：

D O I：

10.1021/om0205243

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(Z)-Alkenyl ligands are formed by insertion of 1-alkynes into bridging hydrides. The unusual stereoselectivity of this elementary step may account for the selectivity toward (Z)-alkenylsilanes frequently observed in 1-alkyne hydrosilylations catalyzed by basic late-transition-metal complexes.

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收藏

页码：4027 / 4029

页数：3

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