Syntheses and spectroscopic studies on zinc(II) and mercury(II) complexes of isatin-3-thiosemicarbazone

被引：26

作者：

Akinchan, NT

Drozdzewski, PM

Holzer, W

机构：

[1] Wroclaw Univ Technol, Inst Inorgan Chem, PL-50370 Wroclaw, Poland

[2] Univ Calabar, Dept Chem, Calabar, Nigeria

[3] Univ Vienna, Inst Pharmaceut Chem, A-1090 Vienna, Austria

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2002年 / 641卷 / 01期

关键词：

thiosemicarbazone; zinc(II) and mercury(II) complexes; IR; Raman; UV-vis; NMR spectra;

D O I：

10.1016/S0022-2860(02)00134-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zinc(II) and mercury(II) complexes were prepared by reacting isatin-3-thiosemicarbazone (ISTSCH) with zinc(II) acetate or mercury(II) bromide. The complexes were characterized by IR, Raman, diffuse reflectance, H-1 and C-13 NMR spectra and elemental analysis. Tetrahedral structures for Zn(ISTSC)(2) and Hg(ISTSCH)Br-2 are suggested. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：17 / 22

页数：6

共 19 条

[1]

Akinchan NT, 2000, POL J CHEM, V74, P1221

[2]

[Anonymous], 1964, INTERPRETED INFRARED, V1

[3] SUBSTITUTED OXINDOLES .I. PREPARATION AND SPECTRAL CHARACTERISTICS OF SOME SIMPLE OXINDOLE DERIVATIVES [J].