IR- and UV-spectral study of palladium (II) complexes with 2-aminipyridine obtained in sulphuric acid and alkaline solutions

被引：3

作者：

Arnaudov, M ^{[1
]}

Dinkov, S ^{[1
]}

Shishkova, L ^{[1
]}

Pindeva, L ^{[1
]}

Petrov, C ^{[1
]}

Dobreva, E ^{[1
]}

机构：

[1] TECH UNIV,SOFIA 1156,BULGARIA

来源：

SPECTROSCOPY LETTERS | 1997年 / 30卷 / 08期

关键词：

2-aminopyridine; Pd (II) complexes; IR- and UV-spectra;

D O I：

10.1080/00387019708006746

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

When obtained in sulphuric acid medium sulphato-2-aminopyridine-palladium (II) complex has a polynuclear structure, with a bridging coordination of both the sulphate-group and 2-aminopyridine. The complex keeps its polynuclear structure in alkaline solution, in which the substitution of sulphate ions by hydroxylic groups yields hydroxo-2-aminopyridine-palladium (II). The compounds discussed are the main components of activators used in currentless metallization of non-conducting surfaces.

引用

页码：1595 / 1607

页数：13

共 18 条

[1] INFRARED-SPECTRA OF SILVER COMPLEXES WITH 2-AMINOPYRIDINE AND CRYSTAL-STRUCTURE OF THE 4-3 AMINOPYRIDINE SILVER-NITRATE COMPOUND [J].