Solid Polymer Electrolyte Water Electrolyser Based on Nafion-TiO2 Composite Membrane for High Temperature Operation

被引：74

作者：

Baglio, V. ^{[2
]}

Ornelas, R. ^{[1
]}

Matteucci, F. ^{[1
]}

Martina, F. ^{[1
]}

Ciccarella, G. ^{[3
,4
]}

Zama, I. ^{[1
]}

Arriaga, L. G. ^{[5
]}

Antonucci, V. ^{[2
]}

Arico, A. S. ^{[2
]}

机构：

[1] Tozzi Renewable Energy SpA, I-48010 Mezzano, RA, Italy

[2] ITAE, CNR, I-98126 Messina, Italy

[3] Univ Salento, INFM, CNR, NNL,Distretto Tecnol ISUFI, I-73100 Lecce, Italy

[4] Univ Salento, Dipartimento Ingn Innovaz, I-73100 Lecce, Italy

[5] Ctr Invest & Desarrollo Tecnol Electroquim SC, Queretaro Sanfandila 76700, Qro, Mexico

来源：

FUEL CELLS | 2009年 / 9卷 / 03期

关键词：

Composite Membrane; High Temperature; SPE Electrolyser; TiO2; Water Electrolysis; INORGANIC FILLERS; FUEL-CELL; EVOLUTION; HYDROGEN; ELECTROCATALYSIS; PERFORMANCE; OXIDATION; BEHAVIOR; OXIDE;

D O I：

10.1002/fuce.200800063

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

070208 [无线电物理];

摘要：

A composite Nafion-TiO2 membrane was manufactured by a recast procedure, using an in-house prepared TiO2. This membrane has shown promising properties for high temperature operation in an SPE electrolyser allowing to achieve higher performance with respect to a commercial Nafion 115 membrane. This effect is mainly due to the water retention properties of the TiO2 filler. A promising increase in electrical efficiency was recorded at low current densities for the composite membrane-based SPE electrolyser at high temperature compared to conventional membrane-based devices.

引用

页码：247 / 252

页数：6

共 25 条

[1]

Silicon oxide Nafion composite membranes for proton-exchange membrane fuel cell operation at 80-140° C [J].