Feasibility study of using microfluidic platforms for visualizing bubble flows in electrolyzer gas diffusion layers

被引:129
作者
Arbabi, F. [1 ]
Kalantarian, A. [1 ,2 ]
Abouatallah, R. [3 ]
Wang, R. [3 ]
Wallace, J. S. [2 ]
Bazylak, A. [1 ]
机构
[1] Univ Toronto, Fac Appl Sci & Engn, Dept Mech & Ind Engn, Thermofluids Energy & Adv Mat TEAM Lab, Toronto, ON M5S 3G8, Canada
[2] Univ Toronto, Fac Appl Sci & Engn, Dept Mech & Ind Engn, Engine Res & Dev Lab, Toronto, ON M5S 3G8, Canada
[3] Hydrogenics Corp, Mississauga, ON L5T 2N6, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
PEM electrolyzer; Bubble visualizations; Microfluidic network; GDL; Porosity distribution; PORE-NETWORK MODELS; POROUS-MEDIA; 2-PHASE FLOW; WATER TRANSPORT; POROSITY;
D O I
10.1016/j.jpowsour.2014.02.042
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
In this study, microfluidic platforms were used to visualize air bubble transport in two-dimensional (2D) representations of gas diffusion layers (GDLs) to gain insight into how the geometric features of the GDL impact multiphase flow in polymer electrolyte membrane (PEM) electrolyzers. Two-dimensional porous networks were designed using volumetric pore space information, including average porosity and average throat size obtained from micro-computed tomography (micro CT) visualizations. Microfluidic chips were fabricated to represent felt, sintered powder, and foam GDLs and used to simulate the transfer of oxygen bubbles generated at the catalyst layer, through the GDL towards the flow channels of a PEM electrolyzer. The results of this work indicate that the use of microfluidic platforms for evaluating PEM electrolyzer GDLs is highly promising. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:142 / 149
页数:8
相关论文
共 44 条
[1]
Network extraction from sandstone and carbonate pore space images [J].
Al-Kharusi, Anwar S. ;
Blunt, Martin J. .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2007, 56 (04) :219-231
[2]
A pore-scale investigation of a multiphase porous media system [J].
Al-Raoush, RI ;
Willson, CS .
JOURNAL OF CONTAMINANT HYDROLOGY, 2005, 77 (1-2) :67-89
[3]
[Anonymous], 1992, NUCL MAGNETIC RESONA
[4]
Experimental study of the effects of hydraulic gradient and injected-gas flow rate on fragmentation in porous media [J].
Baouab, Z. ;
Najjari, M. ;
Ouerfelli, H. ;
Ben Nasrallah, S. .
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING, 2007, 59 (3-4) :250-256
[5]
Barbir F, 2005, SUSTAIN WORLD SER, P1
[6]
Numerical and microfluidic pore networks: Towards designs for directed water transport in GDLs [J].
Bazylak, A. ;
Berejnov, V. ;
Markicevic, B. ;
Sinton, D. ;
Djilali, N. .
ELECTROCHIMICA ACTA, 2008, 53 (26) :7630-7637
[7]
Lab-on-chip methodologies for the study of transport in porous media: energy applications [J].
Berejnov, Viatcheslav ;
Djilali, Ned ;
Sinton, David .
LAB ON A CHIP, 2008, 8 (05) :689-693
[8]
Fractal Flow Patterns in Hydrophobic Microfluidic Pore Networks: Experimental Modeling of Two-Phase Flow in Porous Electrodes [J].
Berejnov, Viatcheslav ;
Bazylak, Aimy ;
Sinton, David ;
Djilali, Ned .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (05) :B760-B767
[9]
Detailed physics, predictive capabilities and macroscopic consequences for pore-network models of multiphase flow [J].
Blunt, MJ ;
Jackson, MD ;
Piri, M ;
Valvatne, PH .
ADVANCES IN WATER RESOURCES, 2002, 25 (8-12) :1069-1089
[10]
Flow in porous media - pore-network models and multiphase flow [J].
Blunt, MJ .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2001, 6 (03) :197-207