A mild ring opening fluorination of epoxide with ionic liquid 1-ethyl-3-methylimidazorium oligo hydrogenfluoride (EMIMF(HF)2.3)

被引：36

作者：

Yoshino, H

Nomura, K

Matsubara, S ^{[1
]}

Oshima, K

Matsumoto, K

Hagiwara, R

Ito, Y

机构：

[1] Kyoto Univ, Dept Chem Mat, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] Kyoto Univ, Dept Fundamental Energy Sci, Grad Sch Energy Sci, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 07期

关键词：

fluorohydrin; epoxide ring opening; hydrogen fluoride; ionic liquid;

D O I：

10.1016/j.jfluchem.2004.02.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Ring opening fluorination of epoxides with hydrogen fluoride in ionic liquid 1-ethyl-3-methylimidazorium oligo hydrogenfluoride EMIMF(HF)(2.3) was demonstrated. This ionic liquid released hydrogen fluoride graduately to make mild conditions without oligomerization of epoxides. (C) 2004 Elsevier B.V. All rights reserved.

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页码：1127 / 1129

页数：3

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