Two alternative, convenient routes to bis(diphenylacetylene)platinum(0)

被引：15

作者：

Huber, C

Kokil, A

Caseri, WR

Weder, C

机构：

[1] Swiss Fed Inst Technol, Inst Polymers, Dept Mat, CH-8092 Zurich, Switzerland

[2] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 18期

关键词：

D O I：

10.1021/om020230h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new synthetic, routes are presented that allow the convenient preparation and isolation of bis(diphenylacetylene)platinum(0) under ambient conditions. The first procedure is based on a ligand exchange reaction between Ph-CdropC-Ph and tris(styrene)platinum(0). The second framework relies on the reduction of cis-[PtCl2(PhCH=CH2)(2)] with triphenylsilane in the presence of diphenylacetylene.

引用

页码：3817 / 3818

页数：2

共 11 条

[1]

Abel E.W., 1995, COMPREHENSIVE ORGANO, V9, P533

[2] HYDROSILYLATION WITH PLATINUM COMPLEXES - PREPARATION, LOW-TEMPERATURE NMR-SPECTRA, AND X-RAY CRYSTAL-STRUCTURE OF THE NOVEL BIS-OLEFIN CATALYST CIS-PTCL2(PHCH=CH2)2 [J].