Rh-complex promoted synthesis of poly(arylacetylene) with pendant TTF units and formation of CT complexes of the polymer with π-acceptors

被引：10

作者：

Shimizu, T ^{[1
]}

Yamamoto, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

来源：

INORGANICA CHIMICA ACTA | 1999年 / 296卷 / 01期

关键词：

Rh(mu-Cl)(eta(4)-norbornadiene)](2); tetrathiafulvalene; CT complexes; pi-acceptors; polymer;

D O I：

10.1016/S0020-1693(99)00358-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Rh(mu-Cl)(eta(4)-norbornadiene)](2) catalyzes the polymerization of an acetylene having a tetrathiafulvalene unit linked through a -CH(2)OCH(2)- group. The polymer obtained has a high molecular weight, good solubility in organic solvents and high chemical stability in air. The polymer forms charge-transfer complexes with 7,7,8,8-tetracyanoquinodimethane and tetrafluorotetracyanoquinodimethane, and the complexes show semiconductivity. Spectroscopic data of the polymer are given. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

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页码：278 / 280

页数：3

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