Humidity effect on baseline conductance and H2S sensitivity of cadmium germanium oxynitride thick film gas sensors

被引:14
作者
Merdrignac-Conanec, O [1 ]
Bernicot, Y [1 ]
Guyader, J [1 ]
机构
[1] Univ Rennes 1, Lab Verres & Ceram, UMR CNRS 6512, F-35042 Rennes, France
关键词
cadmium germanium oxynitride; gas sensor; humidity effect; H2S detection; sensitivity; baseline conductance;
D O I
10.1016/S0925-4005(00)00302-6
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Cadmium germanium oxynitrides are excellent sensing materials for the detection of H2S. The effect of humidity on both the baseline conductance and on the sensitivity to H2S of thick-film gas sensors was investigated The devices were subjected to dry and moist (varying relative humidity (RH)) air. Results showed that, unlike most semiconductor gas detectors, the presence of moisture has no significant effect on conductivity nor on the sensitivity to H2S of cadmium germanium oxynitride sensors. Hypotheses on surface processes accounting for such insensitivity are given. It appears likely that the surface states involved in responses to changes in RH are different from those involved in the detection of other gases. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:86 / 90
页数:5
相关论文
共 17 条
[1]   EFFECTS OF CO, WATER-VAPOR AND SURFACE-TEMPERATURE ON CONDUCTIVITY OF A SNO2 GAS SENSOR [J].
BOYLE, JF ;
JONES, KA .
JOURNAL OF ELECTRONIC MATERIALS, 1977, 6 (06) :717-733
[2]   Investigation, for NH3 gas sensing applications, of the Nb2O5 semiconducting oxide in the presence of interferent species such as oxygen and humidity [J].
Chambon, L ;
Maleysson, C ;
Pauly, A ;
Germain, JP ;
Demarne, V ;
Grisel, A .
SENSORS AND ACTUATORS B-CHEMICAL, 1997, 45 (02) :107-114
[3]  
EUGENE CL, 1995, THESIS RENNES
[4]   MOISTURE EFFECTS ON PURE AND PD-DOPED SNO2 THICK-FILMS ANALYZED BY FTIR SPECTROSCOPY AND CONDUCTANCE MEASUREMENTS [J].
GHIOTTI, G ;
CHIORINO, A ;
MARTINELLI, G ;
CAROTTA, MC .
SENSORS AND ACTUATORS B-CHEMICAL, 1995, 25 (1-3) :520-524
[5]  
HEILAND G, 1982, SENSOR ACTUATOR, V2, P343, DOI 10.1016/0250-6874(81)80055-8
[6]  
JARNOIS D, 1992, THESIS RENNES
[7]   SURFACE PROCESSES IN THE DETECTION OF REDUCING GASES WITH SNO2-BASED DEVICES [J].
KOHL, D .
SENSORS AND ACTUATORS, 1989, 18 (01) :71-113
[8]  
MADOU MJ, 1989, CHEM SENSING SOLID S, P155
[9]  
MADOU MJ, 1989, CHEM SENSING SOLID S, P101
[10]   TIN DIOXIDE GAS SENSORS .1. ASPECTS OF THE SURFACE-CHEMISTRY REVEALED BY ELECTRICAL CONDUCTANCE VARIATIONS [J].
MCALEER, JF ;
MOSELEY, PT ;
NORRIS, JOW ;
WILLIAMS, DE .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1987, 83 :1323-1346