Stabilization of the cubic phase of HfO2 by Y addition in films grown by metal organic chemical vapor deposition

被引:91
作者
Rauwel, E.
Dubourdieu, C.
Hollander, B.
Rochat, N.
Ducroquet, F.
Rossell, M. D.
Van Tendeloo, G.
Pelissier, B.
机构
[1] Ecole Natl Super Phys Grenoble, Mat & Genie Phys Lab, CNRS, UMR 5628, F-38402 St Martin Dheres, France
[2] Forschungszentrum Julich, Ctr Nanoelect Syst Infromat Technol, D-52425 Julich, Germany
[3] Forschungszentrum Julich, ISG1, D-52425 Julich, Germany
[4] CEA, DRT, DPTS, SCPIO,LCPO, F-38054 Grenoble, France
[5] IMEP, F-38016 Grenoble, France
[6] Univ Antwerp, EMAT, B-2020 Antwerp, Belgium
[7] LTM, F-38054 Grenoble 9, France
关键词
D O I
10.1063/1.2216102
中图分类号
O59 [应用物理学];
学科分类号
摘要
Addition of yttrium in HfO2 thin films prepared on silicon by metal organic chemical vapor deposition is investigated in a wide compositional range (2.0-99.5 at. %). The cubic structure of HfO2 is stabilized for 6.5 at. %. The permittivity is maximum for yttrium content of 6.5-10 at. %; in this range, the effective permittivity, which results from the contribution of both the cubic phase and silicate phase, is of 22. These films exhibit low leakage current density (5x10(-7) A/cm(2) at -1 V for a 6.4 nm film). The cubic phase is stable upon postdeposition high temperature annealing at 900 degrees C under NH3. (c) 2006 American Institute of Physics.
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页数:3
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