Real-time monitoring of microwave-promoted organometallic ligand-substitutionreactions using in situ Raman spectroscopy

被引：36

作者：

Barnard, Thomas M.

Leadbeater, Nicholas E.

机构：

[1] Univ Connecticut, Dept Chem, Storrs, CT 06269 USA

[2] CEM Microwave Technol, Matthews, NC 28104 USA

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 34期

关键词：

D O I：

10.1039/b608793k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An apparatus has been developed for real-time monitoring of organometallic reactions under microwave irradiation using in situ Raman spectroscopy and its application for monitoring ligand substitution reactions of Mo(CO)(6) demonstrated.

引用

页码：3615 / 3616

页数：2

共 20 条

[1] Organometallic chemistry in a conventional microwave oven: the facile synthesis of group 6 carbonyl complexes [J].

Ardon, M ;

Hogarth, G ;

Oscroft, DTW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (15) :2429-2435

[2] APPLICATION OF MICROWAVE DIELECTRIC LOSS HEATING EFFECTS FOR THE RAPID AND CONVENIENT SYNTHESIS OF ORGANOMETALLIC COMPOUNDS [J].

BAGHURST, DR ;

MINGOS, DMP ;

WATSON, MJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 368 (03) :C43-C45

[3] APPLICATION OF MICROWAVE DIELECTRIC LOSS HEATING EFFECTS FOR THE RAPID AND CONVENIENT SYNTHESIS OF COORDINATION-COMPOUNDS [J].

BAGHURST, DR ;

COOPER, SR ;

GREENE, DL ;

MINGOS, DMP ;

REYNOLDS, SM .

POLYHEDRON, 1990, 9 (06) :893-895

[4] APPLICATIONS OF FOURIER-TRANSFORM RAMAN-SPECTROSCOPY IN INORGANIC-CHEMISTRY - A CONSIDERED VIEW [J].

DAY, TN ;

HENDRA, PJ ;

REST, AJ ;

ROWLANDS, AJ .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1991, 47 (9-10) :1251-1262

[5] SIMULTANEOUS MONITORING OF AMORPHOUS AND CRYSTALLINE PHASES IN SILICALITE PRECURSOR GELS - AN IN-SITU HYDROTHERMAL AND TIME-RESOLVED SMALL-ANGLE AND WIDE-ANGLE X-RAY-SCATTERING STUDY [J].

DOKTER, WH ;

BEELEN, TPM ;

VANGARDEREN, HF ;

VANSANTEN, RA ;

BRAS, W ;

DERBYSHIRE, GE ;

MANT, GR .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :901-906

[6] Ultrafast charge separation in a photoreactive rhenium-appended porphyrin assembly monitored by picosecond transient infrared spectroscopy [J].

Gabrielsson, A ;

Hartl, F ;

Zhang, H ;

Smith, JRL ;

Towrie, M ;

Vlcek, A ;

Perutz, RN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (13) :4253-4266

[7] Excited states of transition metal complexes studied by time-resolved infrared spectroscopy [J].

George, MW ;

Turner, JJ .

COORDINATION CHEMISTRY REVIEWS, 1998, 177 :201-217

[8] Remote analysis using IR glass fibers [J].

Hocdé, S ;

Boussard-Plédel, C ;

Le Coq, D ;

Fonteneau, G ;

Lucas, J .

INFRARED OPTICAL FIBERS AND THEIR APPLICATIONS, 1999, 3849 :50-59

[9] Controlled microwave heating in modern organic synthesis [J].

Kappe, CO .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (46) :6250-6284

[10]

Kuhnert N, 2002, J CHEM RES-S, P66

← 1 2 →