Hydrocarbon uptake in the alkylated micropores of a columnar supramolecular solid

被引：28

作者：

Taylor, Thomas J. ^{[1
]}

Bakhmutov, Vladimir L. ^{[1
]}

Gabbai, Francois P. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 42期

关键词：

adsorption; alkanes; mercury; microporous materials; supramolecular chemistry;

D O I：

10.1002/anie.200602440

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Neither Doric, Ionic, nor Corinthian! (HgC6F4)3 interacts with 1,3,5-(Me 3SiC≡ C)3C6H3 to form columns with peripheral trimethylsilyl groups. These columns self-aggregate into a hexagonal solid containing pores lined by nonpolar methyl groups (see picture; Hg orange, Si purple, C gray, F green, H white), which can adsorb alkanes reversibly. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7030 / 7033

页数：4

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