Reversible red fluorescent molecular switches

被引:153
作者
Bossi, Mariano [1 ]
Belov, Vladimir [1 ]
Polyakova, Svetlana [1 ]
Hell, Stefan W. [1 ]
机构
[1] Max Planck Inst Biophys Chem, Dept Nanobiophoton, D-37077 Gottingen, Germany
关键词
fluorescence modulation; heterocycles; molecular switches; photochromism; rhodamines;
D O I
10.1002/anie.200602591
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
I see red, I see red, I see red: Optically switchable compounds were synthesized whose visible fluorescence can be quenched down to 6% with light at 360-400 nm and then restored with red light from a diode laser. The molecular switch offers potential applications in data storage and far-field microscopy with spatial resolution far below the diffraction limit. (Chemical Equation Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7462 / 7465
页数:4
相关论文
共 41 条
  • [1] Highly fluorescent and photochromic diarylethene oligomer bridged by p-phenylenevinylene
    Cho, H
    Kim, E
    [J]. MACROMOLECULES, 2002, 35 (23) : 8684 - 8687
  • [2] Crano JC, 1999, T APPL CHEM, V1, P1
  • [3] Optical ON/OFF switching of intramolecular photoinduced charge separation in a donor-bridge-acceptor system containing dithienylethene
    Endtner, JM
    Effenberger, F
    Hartschuh, A
    Port, H
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (13) : 3037 - 3046
  • [4] Reaction dynamics of a photochromic fluorescing dithienylethene
    Ern, J
    Bens, AT
    Martin, HD
    Mukamel, S
    Tretiak, S
    Tsyganenko, K
    Kuldova, K
    Trommsdorff, HP
    Kryschi, C
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2001, 105 (10) : 1741 - 1749
  • [5] Feringa B.L., 2001, Molecular Switches
  • [6] Fernández-Acebes A, 1999, CHEM-EUR J, V5, P3285, DOI 10.1002/(SICI)1521-3765(19991105)5:11<3285::AID-CHEM3285>3.0.CO
  • [7] 2-Q
  • [8] Modulation of the absorption, fluorescence, and liquid-crystal properties of functionalised diarylethene derivatives
    Frigoli, M
    Mehl, GH
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (20) : 5243 - 5250
  • [9] Digital photoswitching of fluorescence based on the photochromism of diarylethene derivatives at a single-molecule level
    Fukaminato, T
    Sasaki, T
    Kawai, T
    Tamai, N
    Irie, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) : 14843 - 14849
  • [10] Diheteroarylethenes as thermally stable photoswitchable acceptors in photochromic fluorescence resonance energy transfer (pcFRET)
    Giordano, L
    Jovin, TM
    Irie, M
    Jares-Erijman, EA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (25) : 7481 - 7489