Modification of 2D water that contains hexameric units in chair and boat conformations -: A contribution to the structural elucidation of bulk water

被引：163

作者：

Rodríguez-Cuamatzi, P ^{[1
]}

Vargas-Díaz, G ^{[1
]}

Höpfl, H ^{[1
]}

机构：

[1] Univ Autonoma Estado Morelos, Ctr Invest Quim, Cuernavaca, Morelos, Mexico

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 23期

关键词：

boron; hydrogen bonds; structure elucidation; supramolecular chemistry; water chemistry;

D O I：

10.1002/anie.200453957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemistry that holds water: A honey-comblike water sheet having a hitherto unknown structure is described. The crystal lattice of bulk water in the presence of 1,4-phenylenediboronic acid (see picture) contains hexameric rings with chair and boat conformations. The hydrogen-bonding pattern is completely elucidated and gives two different motifs for each of the three independent hydrogen-bonded rings.

引用

页码：3041 / 3044

页数：4

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