Synthesis of 1,1′-binaphthyl-based enantiopure C60 dimers

被引：25

作者：

Giacalone, F ^{[1
]}

Segura, JL ^{[1
]}

Martín, N ^{[1
]}

机构：

[1] Univ Complutense, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2002年 / 67卷 / 10期

关键词：

D O I：

10.1021/jo020088u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first enantiomerically pure and soluble C-60 dimers have been synthesized from suitably functionalized 1,1'-binaphthyl derivatives by 1,3-dipolar cycloaddition of the respective in situ generated diazo compounds to C-60. These systems exhibit optical and electrochemical activity.

引用

页码：3529 / 3532

页数：4

共 39 条

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