Poly[bis[2-(1-cyclohexenyl)ethylammonium] di-μ-iodo-diodo-plumbate(II)]

被引:30
作者
Billing, David G. [1 ]
Lemmerer, Andreas [1 ]
机构
[1] Univ Witwatersrand, Sch Chem, ZA-2050 Wits, South Africa
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷 / 07期
关键词
D O I
10.1107/S0108270106013953
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, (C8H16N)(2)[PbI4], crystallizes as an inorganic-organic hybrid perovskite, adopting the unusual 2a(p) x 2a(p) superstructure. As such, the structure consists of two-dimensional sheets of corner-sharing PbI6 octahedra in the ab plane, separated by bilayers of 2-(1-cyclohexenyl) ethylammonium cations. The ethylammonium groups are not in the plane of the cyclohexenyl rings.
引用
收藏
页码:M269 / M271
页数:3
相关论文
共 10 条
[1]  
BRANDENBURG K, 1999, DIAMOND VERSION 2 1E
[2]  
*BRUK AXS INC, 1998, SMART NT VERS 5 050
[3]  
*BRUK AXS INC, 1999, SAINT PLUS VERS 6 02
[5]  
Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020
[6]   Highly efficient electroluminescence from a heterostructure device combined with emissive layered-perovskite and an electron-transporting organic compound [J].
Hattori, T ;
Taira, T ;
Era, M ;
Tsutsui, T ;
Saito, S .
CHEMICAL PHYSICS LETTERS, 1996, 254 (1-2) :103-108
[7]   Synthesis, structure, and properties of organic-inorganic perovskites and related materials [J].
Mitzi, DB .
PROGRESS IN INORGANIC CHEMISTRY, VOL 48, 1999, 48 :1-121
[8]   A layered solution crystal growth technique and the crystal structure of (C6H5C2H4NH3)2PbCl4 [J].
Mitzi, DB .
JOURNAL OF SOLID STATE CHEMISTRY, 1999, 145 (02) :694-704
[9]  
Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination
[10]   Single-crystal structure validation with the program PLATON [J].
Spek, AL .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13