Poly[bis[2-(1-cyclohexenyl)ethylammonium] di-μ-iodo-diodo-plumbate(II)]

被引：30

作者：

Billing, David G. ^{[1
]}

Lemmerer, Andreas ^{[1
]}

机构：

[1] Univ Witwatersrand, Sch Chem, ZA-2050 Wits, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷 / 07期

关键词：

D O I：

10.1107/S0108270106013953

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, (C8H16N)(2)[PbI4], crystallizes as an inorganic-organic hybrid perovskite, adopting the unusual 2a(p) x 2a(p) superstructure. As such, the structure consists of two-dimensional sheets of corner-sharing PbI6 octahedra in the ab plane, separated by bilayers of 2-(1-cyclohexenyl) ethylammonium cations. The ethylammonium groups are not in the plane of the cyclohexenyl rings.

引用

页码：M269 / M271

页数：3

共 10 条

[1]

BRANDENBURG K, 1999, DIAMOND VERSION 2 1E

[2]

*BRUK AXS INC, 1998, SMART NT VERS 5 050

[3]

*BRUK AXS INC, 1999, SAINT PLUS VERS 6 02

[4] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

[5]

Farrugia L. J., 1999, J. Appl. Crystallogr, V32, P837, DOI DOI 10.1107/S0021889899006020

[6] Highly efficient electroluminescence from a heterostructure device combined with emissive layered-perovskite and an electron-transporting organic compound [J].

Hattori, T ;

Taira, T ;

Era, M ;

Tsutsui, T ;

Saito, S .

CHEMICAL PHYSICS LETTERS, 1996, 254 (1-2) :103-108

[7] Synthesis, structure, and properties of organic-inorganic perovskites and related materials [J].

Mitzi, DB .

PROGRESS IN INORGANIC CHEMISTRY, VOL 48, 1999, 48 :1-121

[8] A layered solution crystal growth technique and the crystal structure of (C6H5C2H4NH3)2PbCl4 [J].

Mitzi, DB .

JOURNAL OF SOLID STATE CHEMISTRY, 1999, 145 (02) :694-704

[9]

Sheldrick G., 2017, SHELX2017, Programs for Crystal Structure Determination

[10] Single-crystal structure validation with the program PLATON [J].

Spek, AL .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :7-13

← 1 →