Magnesia-carbon nanotubes (MgO-CNTs) nanocomposite:: novel support of Ru catalyst for the generation of COx-free hydrogen from ammonia

被引:122
作者
Yin, SF
Xu, BQ [1 ]
Wang, SJ
Ng, CF
Au, CT
机构
[1] Tsing Hua Univ, Dept Chem, Innovat Catalysis Program, Key Lab Organ Elect & Mol Engn, Beijing 100084, Peoples R China
[2] Xiamen Univ, Anal & Testing Ctr, Xiamen 361005, Peoples R China
[3] Hong Kong Baptist Univ, Ctr Surface Anal & Res, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
[4] Xiamen Univ, Anal & Testing Ctr, Xiamen 361005, Peoples R China
基金
美国国家科学基金会;
关键词
magnesia-carbon nanotubes nanocomposite; ruthenium catalyst; ammonia decomposition; hydrogen manufacture;
D O I
10.1023/B:CATL.0000030107.64702.74
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Magnesia - carbon nanotubes (abbreviated as MgO - CNTs) nanocomposites were prepared by impregnation of CNTs with Mg(NO3)(2) .6H(2)O in ethanol solution, followed by drying at 353 K and calcination at 873 K, respectively. The nanocomposites are thermally more stable than CNTs in a H-2 flow. The use of the nanocomposites as support yielded more efficient Ru catalysts for the generation of COx-free hydrogen from NH3 decomposition.
引用
收藏
页码:113 / 116
页数:4
相关论文
共 21 条
[1]   Molecular sensing techniques for the characterization and design of new ammonia catalysts [J].
Aika, K ;
Kubota, J ;
Kadowaki, Y ;
Niwa, Y ;
Izumi, Y .
APPLIED SURFACE SCIENCE, 1997, 121 :488-491
[2]   SUPPORT AND PROMOTER EFFECT OF RUTHENIUM CATALYST .2. RUTHENIUM ALKALINE-EARTH CATALYST FOR ACTIVATION OF DINITROGEN [J].
AIKA, K ;
OHYA, A ;
OZAKI, A ;
INOUE, Y ;
YASUMORI, I .
JOURNAL OF CATALYSIS, 1985, 92 (02) :305-311
[3]   Carbon monoxide poisoning of proton exchange membrane fuel cells [J].
Baschuk, JJ ;
Li, XG .
INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2001, 25 (08) :695-713
[4]   Kinetics of NH3 decomposition over well dispersed Ru [J].
Bradford, MCJ ;
Fanning, PE ;
Vannice, MA .
JOURNAL OF CATALYSIS, 1997, 172 (02) :479-484
[5]   Materials and processes for small fuel cells [J].
Chang, H ;
Kim, JR ;
Cho, JH ;
Kim, HK ;
Choi, KH .
SOLID STATE IONICS, 2002, 148 (3-4) :601-606
[6]   Ammonia decomposition kinetics over Ni-Pt/Al2O3 for PEM fuel cell applications [J].
Chellappa, AS ;
Fischer, CM ;
Thomson, WJ .
APPLIED CATALYSIS A-GENERAL, 2002, 227 (1-2) :231-240
[7]   Hydrogen storage in carbon nanotubes [J].
Cheng, HM ;
Yang, QH ;
Liu, C .
CARBON, 2001, 39 (10) :1447-1454
[8]   CO-free fuel processing for fuel cell applications [J].
Choudhary, TV ;
Goodman, DW .
CATALYSIS TODAY, 2002, 77 (1-2) :65-78
[9]   Catalytic ammonia decomposition:: COx-free hydrogen production for fuel cell applications [J].
Choudhary, TV ;
Sivadinarayana, C ;
Goodman, DW .
CATALYSIS LETTERS, 2001, 72 (3-4) :197-201
[10]  
Fouletier J, 2002, ACTUAL CHIMIQUE, P138