Photoinduced electron transfer and redox-type photochromism of a TiO2-anchored molecular diad

被引：35

作者：

Bonhote, P

Moser, JE

Vlachopoulos, N

Walder, L

Zakeeruddin, SM

HumphryBaker, R

Pechy, P

Gratzel, M

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 10期

关键词：

D O I：

10.1039/cc9960001163

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A linear, rigid molecular diad constituted of an electron donor (triarylamine, D) linked to a chromophore [Ru-bis(terpyridine), S] is synthesized; upon anchoring onto a nanocrystalline TiO2 electrodes this produces a charge-separated state D+-S \(e-) TiO2 under illumination decaying with: k = 7 X 10(7) s(-1) (70%), 3 X 10(5) s(-1) (20%) and 4 x 10(3) s(-1) (10%) and yielding a photochromic effect at positive polarization.

引用

页码：1163 / 1164

页数：2

共 11 条

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