Microwave-assisted preparation of amides using a stable and reusable mesoporous carbonaceous solid acid

被引:39
作者
Luque, Rafael [1 ]
Budarin, Vitaly [1 ]
Clark, James H. [1 ]
Macquarrie, Duncan J. [1 ]
机构
[1] Univ York, Green Chem Ctr Excellence, York YO10 5DD, N Yorkshire, England
关键词
SUPPORTED REAGENTS SSRS; CARBOXYLIC-ACIDS; BOND FORMATION; AMINES; ACYLATION; CHEMISTRY; EFFICIENT; IRRADIATION; CATALYSTS; ALCOHOLS;
D O I
10.1039/b821392p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient and green microwave assisted protocol to prepare amides from amines via N-acylation using acidic polysaccharide derived mesoporous materials provides quantitative yields of amides in short reaction times.
引用
收藏
页码:459 / 461
页数:3
相关论文
共 39 条
[1]   Synthesis, evaluation and application of novel bifunctional N,N-di-isopropylbenzylamineboronic acid catalysts for direct amide formation between carboxylic acids and amines [J].
Arnold, Kenny ;
Batsanov, Andrei S. ;
Davies, Bryan ;
Whiting, Andrew .
GREEN CHEMISTRY, 2008, 10 (01) :124-134
[2]   To catalyze or not to catalyze? Insight into direct amide bond formation from amines and carboxylic acids under thermal and catalyzed conditions [J].
Arnold, Kenny ;
Davies, Bryan ;
Giles, Richard L. ;
Grosjean, Christophe ;
Smith, Gillian E. ;
Whiting, Andrew .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (7-8) :813-820
[3]   New, efficient, selective, and one-pot method for acylation of amines [J].
Basanagouda, Mahantesha ;
Kulkarni, Manohar V. ;
Kalkhambkar, Raj G. ;
Kulkarni, Geeta M. .
SYNTHETIC COMMUNICATIONS, 2008, 38 (17) :2929-2940
[4]   Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties [J].
Budarin, Vitaly ;
Clark, James H. ;
Hardy, Jeffrey J. E. ;
Luque, Rafael ;
Milkowski, Krzysztof ;
Tavener, Stewart J. ;
Wilson, Ashley J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) :3782-3786
[5]   Tunable mesoporous materials optimised for aqueous phase esterifications [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Luque, Rafael ;
Macquarrie, Duncan J. ;
Koutinas, Apostolis ;
Webb, Colin .
GREEN CHEMISTRY, 2007, 9 (09) :992-995
[6]   Versatile mesoporous carbonaceous materials for acid catalysis [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Luque, Rafael ;
Macquarrie, Duncan J. .
CHEMICAL COMMUNICATIONS, 2007, (06) :634-636
[7]   Indium(III) chloride as a new, highly efficient, and versatile catalyst for acylation of phenols, thiols, alcohols, and amines [J].
Chakraborti, AK ;
Gulhane, R .
TETRAHEDRON LETTERS, 2003, 44 (35) :6749-6753
[8]   Kinetics of amide formation through Carbodiimide/N-Hydroxybenzotriazole (HOBt) couplings [J].
Chan, Lai C. ;
Cox, Brian G. .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (23) :8863-8869
[9]   Acylation of amines with carboxylic acids: the atom economic protocol catalysed by Fe(III)-montmorillonite [J].
Choudary, BM ;
Bhaskar, V ;
Kantam, ML ;
Rao, KK ;
Raghavan, K .
CATALYSIS LETTERS, 2001, 74 (3-4) :207-211
[10]   Synthesis and structure of potential Lewis acid-Lewis base bifunctional catalysts:: 2-N,N-diisopropylaminophenylboronate derivatives [J].
Coghlan, SW ;
Giles, RL ;
Howard, JAK ;
Patrick, LGF ;
Probert, MR ;
Smith, GE ;
Whiting, A .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (21-22) :4784-4793