Extraordinary high trivalent Al3+ ion conduction in solids

被引：54

作者：

Imanaka, N ^{[1
]}

Hasegawa, Y ^{[1
]}

Yamaguchi, M ^{[1
]}

Itaya, M ^{[1
]}

Tamura, S ^{[1
]}

Adachi, GY ^{[1
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan

来源：

CHEMISTRY OF MATERIALS | 2002年 / 14卷 / 11期

关键词：

D O I：

10.1021/cm020667f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An extraordinary high Al3+ ion conducting solid electrolyte was realized by successfully stabilizing the NASICON-type structure which has a suitable three-dimensional Al3+ ion pass way. Because the Al3+ ion conductivity reaches the ion conductivity region of the well-known and commercially available oxide anion conducting solids, practical applications of the present Al3+ ion conducting (AlxZr1-x)4/(4-x)Nb (PO4)3 solid for functional materials such as chemical sensors, rechargeable batteries, etc., are greatly expected.

引用

页码：4481 / 4483

页数：3

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