Magnetic lanthanide-transition-metal organic-inorganic hybrid materials: From discrete clusters to extended frameworks

被引：327

作者：

Huang, You-Gui ^{[1
]}

Jiang, Fei-Long ^{[1
]}

Hong, Mao-Chun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Optoelect Mat Chem & Phys, Fuzhou 350002, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 23-24期

基金：

中国国家自然科学基金;

关键词：

Lanthanide-transition-metal; Magnetic; Cluster; Framework; Slow relaxation; Hybrid; ONE-DIMENSIONAL CHAIN; SINGLE-MOLECULE MAGNETS; F-BLOCK ELEMENTS; POLYNUCLEAR COPPER(II)-LANTHANIDE(III) COMPLEXES; LADDER-TYPE COMPOUNDS; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; EXCHANGE INTERACTIONS; FERROMAGNETIC INTERACTION;

D O I：

10.1016/j.ccr.2009.05.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Magnetic lanthanide-transition-metal hybrid materials have enjoyed increasing attraction because they not only provide examples for studying magnetic coupling involving lanthanide ions but also exhibit novel magnetic behavior which render them candidates for future devices for information storage and quantum computation. Herein, we review the structures and magnetic properties of lanthanide-transition-metal hybrid materials that are categorized based on the structural features and organic ligands used. The review pays special attention to the examples which show magnetic slow relaxation since these render them to be potentially applied as devices for information storage. (C) 2009 Elsevier B.V. All rights reserved.

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收藏

页码：2814 / 2834

页数：21

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