Palladium-mediated ring opening of hydroxycyclopropanes

被引：120

作者：

Park, SB ^{[1
]}

Cha, JK ^{[1
]}

机构：

[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 02期

关键词：

D O I：

10.1021/ol991250r

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] The palladium-mediated ring opening of substituted cyclopropanols has been found to take place predominantly at the less substituted CC bond. Thus, sequential application of the titanium mediated cyclopropanation of esters and the palladium mediated ring opening of the resulting cyclopropanols provides a convenient method for functionalizing monosubstituted olefins.

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页码：147 / 149

页数：3

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